Complementary colors incite each other to maximum vividness when adjacent and annihilate each other to gray when mixed
Two colors are complementary when their pigment mixture yields neutral gray-black (equivalent to containing all three primaries in suitable proportion). Complementary pairs in Itten’s 12-hue circle: yellow/violet, orange/blue, red/green (plus intermediate pairs). Adjacent complements: (a) intensify each other’s apparent saturation — the maximum mutual vividness; (b) create visual vibration at their boundary. Mixed together: (c) neutralize to gray-black — the opposite effect, complete cancellation. Each complementary pair also often coincides with another contrast: yellow/violet is simultaneously the strongest light-dark contrast; red-orange/blue-green is simultaneously the cold-warm pole pair; red/green are complementary at equal brilliance (no light-dark component). Understanding complementaries is prerequisite to color harmony, simultaneous contrast, and saturation mixing.
Examples
Red next to green in a generative patch creates maximum mutual vividness at the boundary — useful for high-energy visual accents. Mixing red + green pigment (or blending in a shader with multiply mode) approaches dark neutral.
Assessment
Identify the complementary of blue-violet; explain why a red/green pair vibrates at equal brilliance but yellow/violet does not; predict what color two painters will get mixing orange + blue.